Hi all,
I solved the problem myself and post it here in case somebody else needs a solution for this. I just assigned the digital output to the data acquisition interface "dqScanner". When starting the dqScanner interface, both digital and analog output channels are started with synchronization (without any additional command).
[ch1, ixd1] = addoutput(dqScanner, "PXI1Slot2", "ao0", "Voltage");
[ch2, ixd2] = addoutput(dqScanner, "PXI1Slot2", "ao1", "Voltage");
ch3 = addoutput(dqScanner, "PXI1Slot2", "ctr0", "PulseGeneration");
SVoltArray = ...
preload(dqScanner, SVoltArray);
start(dqScanner, 'RepeatOutput');